Also curious as to why you don't want him neutered. There's a LOT of benefits of it; not just to help with mounting but also marking, and sometimes hormonal aggression issues. Neutered boys make the best pets!
Otherwise there's not much you can do other than correcting him every time he starts to do it. But keep in mind, he's not doing it to be mean; he's doing it because his hormones are going crazy. It's a VERY frustrating for an intact male to even have to be around a female, especially one that's unspayed. I wouldn't wish that on any dog... some have used the example of throwing a college boy into a room with a bunch of naked strippers and saying he's not allowed to do anything. He's just doing what comes naturally.... neutering him is going to be your best bet for HIS peace of mind, and it will allow him to be more relaxed and a happier pet in general.
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